Every zone of Shadowlands offers four different tamer challenges that can be active world quests. Completing 14 out of those 16 awards you the achievement Battle in the Shadowlands
and the toy Mawsworn Pet Leash
Most of these tamers are always available to challenge, not only when their world quest is active, and you can challenge them repeatedly. You can find maps on where to find each of these tamers by visiting their specific section and hovering over the map symbol next to the coordinates.
This can be especially useful if you are aiming to complete the achievement Family Exorcist
for which you need to defeat tamers with teams made of pets from specific families only. Strategies for all those combinatins are available in the Family Exorcist section